Vogel's textbook of quantitative chemical analysis - Fifth edition - Revised by G.H. Jeffery and others

Sep 11, 2026

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Vogel's textbook of quantitative chemical analysis, Fifth edition, presents the fundamentals and advanced theory behind performing reliable quantitative determinations in chemistry. It builds from chemical analysis methods, sampling, and instrumental approaches, then develops core reaction-in-solution principles such as equilibrium, solubility, acid-base behavior, complex ions, and redox potentials. It also introduces common laboratory apparatus and basic techniques, and extends coverage to errors, statistics, and sampling to support accurate analytical data treatment.

LanguageEnglish

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Pages906

Reading Time5 h 17 min

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PART A FUNDAMENTALS OF QUANTITATIVE CHEMICAL ANALYSIS

CHAPTER 1 INTRODUCTION

CHAPTER 2 FUNDAMENTAL THEORETICAL PRINCIPLES OF REACTIONS IN SOLUTION

CHAPTER 3 COMMON APPARATUS AND BASIC TECHNIQUES

PART B ERRORS, STATISTICS, AND SAMPLING

CHAPTER 4 ERRORS AND STATISTICS

TEXTBOOK OFQUANTITATIVECHEMICALANALYSIS FIFTH EDITION TEXTB0OK OFQUANTITATIVE CHEMICAL ANALYSIS FIFTH EDITION Revised by the following members ofThe School of Chemistry,Thames Polytechnic,London GH Jeffery,BSc,Ph D,C Chem,FRSC Former Principal Lecturer and Deputy Head of the School of Chemistry J Bassett,M Sc,C Chem,FRSCFormer Senior Lecturer in Inorganic Chemistry J Mendham,MSc,C Chem,MRSC Principal Lecturer in Analytical Chemistry RC Denney,BSc,Ph D,C Chem,FRSC,MBIMPrincipal Lecturer in Organic Chemistry Longman Scientific&TechnicalLongman Group UK LimitedLongman House,Burnt Mill,HarlowEssex CM202JE,Englandand Associated Companies throughout the world Copublished in the United States withJohn Wiley and Sons Inc,605 Third Abenue,New York NY 10158 CLongman Group UK Limited 1978,1989 AM rights reserved;no part ofthe publicationmay be reproduced,stored in a retrieval system,or transmitted in any form or by any means,electronic,mechanical,photocopying,recording,or otherwise,without the prior written permission of the Publishers,or a licence permitting restricted copying in the United Kingdom issued bythe Copyright Licensing Agency Ltd,33-34 Alfred Place,London WC1E 7DP. First published in 1939 New impressions 1941,1942,1943,1944,1945,1946,1947,1948Second edition 1951 New impresions 1953,1955,1957,1958,1959,1960 Third edition 1961(published under the title A Text-book of Quantitative Inorganic AnalysisIncluding Elementary Instrumental Analysis) New impressions 1962,1964,1968,1969,1971,1974,1975Fourth edition 1978 New impressions 1979,1981,1983,1985,1986,1987Fifth edition 1989 British Library Cataloguing in Publication Data Vogel,Arthur Israel Vogel's textbook of quantitative chemicalanalysis.-5th ed. 1.Quantitative analysis I.Title II.Jeffery,G.H. 545 ISBN 0-582-44693-? Library of Congress Cataloguing in Publication Data VogelArthur Israel [Textbook of quantitative chemical analysis] Vogel's textbook of quantitative chemical analysis.-5th ed./revised by….G.H.Jeffery.…[et al.] p. cm. Rev.ed.of:Vogel's textbook of quantitative inorganic analysis4th ed.1978. Includes bibliographies and index.ISBN 0-470-21517-8 1.Chemistry,Analytic-Quantitative.2.Chemistry,Inorganic. I.Jeffery,G.H.1909-.II.Vogel,Arthur Israel.Vogel'stextbook of quantitative inorganic analysis.II.Title. QD101.2.V631989 545-dc20 89-12296 CIP Set in 10/11pt Lasercomp Times New RomanPrinted in Great Britainby Bath Press,Avon CONTENTS PART A FUNDAMENTALS OF QUANTITATIVE CHEMICALANALYSIS CHAPTER 1 INTRODUCTION 1.1 Chemical analysis 3 1.2 Applications of chemical analysis 3 1.3 Sampling 4 1.4 Types of analysis 5 1.5 Use of literature 6 1.6 Common techniques 7 1.7 Instrumental methods 8 1.8 Other techniques 9 1.9 Factors affecting the choice of analytical methods 10 1.10 Interferences 12 1.11 Data acquisition and treatment 13 1.12 Summary 14 CHAPTER 2 FUNDAMENTAL THEORETICAL PRINCIPLES OFREACTIONS IN SOLUTION 2.1 Chemical equilibrium 15 2.2 The law of mass action 16 2.3 Factors affecting chemical reactions in solution 18 2.4 Electrolytic dissociation 19 2.5 Activity and activity coefficient 23 2.6 Solubility product 24 2.7 Quantitative efiects of a common ion 26 2.8 Fractional precipitation 28 2.9 Effect of acids on the solubility of a precipitate 29 2.10 Effect of temperature on the solubility of a precipitate 30 2.11 Effect of the solvent on the solubility of a precipitate 30 2.12 Acid-base equilibria in water 31 2.13 Strengths of acids and bases 31 1 3 2.14 Dissociation of polyprotic acids 33 2.15 Common-ion effect 34 2.16 The ionic product of water 36 2.17 The hydrogen ion exponent 38 2.18 The hydrolysis of salts 40 2.19 Hydrolysis constant and degree of hydrolysis 42 2.20 Buffer solutions 46 2.21 Complex ions 49 2.22 Complexation 51 2.23 Stability of complexes 52 2.24 Metal ion buffers 53 2.25 Factors

FAQs

What topics are covered in Part A of the book?

Part A focuses on fundamentals of quantitative chemical analysis, including an introduction, the theoretical principles of reactions in solution, and common apparatus and basic techniques.

Which theoretical areas are included under the chapter on reactions in solution?

The book addresses chemical equilibrium and mass action, electrolytic dissociation, solubility product and precipitation behavior, acid-base equilibria, complex ions and complexation, and electrode and redox-related potentials.

How does the book help ensure accurate quantitative results?

By combining core theory with practical techniques and then extending into errors, statistics, and sampling, the text supports appropriate data acquisition and treatment to improve analytical reliability.

Sep 11, 2026

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