[{"data":1,"prerenderedAt":-1},["ShallowReactive",2],{"doc-detail-31815":3,"doc-seo-31815":27},{"code":4,"msg":5,"data":6},0,"success",{"doc_id":7,"user_id":8,"nickname":9,"user_avatar":10,"doc_module":4,"category_id":11,"category_name":12,"doc_title":13,"doc_description":14,"file_id":15,"file_url":16,"file_type":17,"file_size":18,"view_count":4,"is_deleted":4,"is_public":19,"is_downloadable":19,"audit_status":19,"page_count":20,"language":21,"language_code":22,"table_of_contents":23,"faqs":24,"seo_title":13,"seo_description":14,"update_tm":25,"read_time":26},31815,1099513958607,"Jiven","https://ap-avatar.wpscdn.com/avatar/100002390cf8733938c?x-image-process=image/resize,m_fixed,w_180,h_180&k=1778829742770036399",8,"Research & Report","Three-in-One Structural Building Mode Based Ti16-Type Titanium Oxo Cluster","Titanium oxo clusters (TOCs) with well-defined molecular structures enable photocatalysis, including photocatalytic degradation, hydrogen production, and water oxidation, yet their hydrolytic stability and light absorption strongly depend on the choice of peripheral organic ligands. Using salicylhydroxamic acid (H3L), two TOCs were solvothermally synthesized and characterized as [Ti8(μ2-O)2(μ3-O)2(OiPr)12(L)4]·2CH3CN (1) and [Ti16(μ2-O)10(μ3-O)4(PhCOO)14(L)6(HL)2]·4CH3CN·2iPrOH (2). Complex 2 replaces alkoxy ligands with multidentate ligands via benzoic acid addition, achieving enhanced hydrolytic stability, a visible-light absorption up to 700 nm, and measurable activity for methyl orange photodegradation.","cbCais9Uv7bkcR5r","https://ap.wps.com/l/cbCais9Uv7bkcR5r","pdf",7481312,1,9,"English","en","# Abstract\n# Introduction\n## Background on titanium oxo clusters\n## Hydrolytic stability challenge and ligand protection\n## Synthesis strategies: post-modification vs one-pot\n## Light absorption and dye-functional ligands\n## Motivation and study design (H3L-derived TOCs)","[{\"question\":\"How does complex 2 perform under visible light for dye degradation?\",\"answer\":\"Complex 2 strongly absorbs visible light up to 700 nm and shows obvious activity for the photodegradation of methyl orange.\"}]",1780261241,23,{"code":4,"msg":28,"data":29},"ok",{"site_id":30,"language":22,"slug":31,"title":13,"keywords":32,"description":14,"schema_data":33,"social_meta":76,"head_meta":78,"extra_data":80,"updated_unix":25},105,"three-in-one-structural-building-mode-based-ti16-type-titanium-oxo-cluster","",{"@graph":34,"@context":75},[35,52,66],{"@type":36,"itemListElement":37},"BreadcrumbList",[38,42,46,49],{"item":39,"name":40,"@type":41,"position":19},"https://docshare.wps.com","Home","ListItem",{"item":43,"name":44,"@type":41,"position":45},"https://docshare.wps.com/document/","Document",2,{"item":47,"name":12,"@type":41,"position":48},"https://docshare.wps.com/document/research-report/",3,{"item":50,"name":13,"@type":41,"position":51},"https://docshare.wps.com/document/three-in-one-structural-building-mode-based-ti16-type-titanium-oxo-cluster/31815/",4,{"url":50,"name":13,"@type":53,"author":54,"headline":13,"publisher":56,"fileFormat":59,"description":14,"dateModified":60,"datePublished":60,"encodingFormat":59,"isAccessibleForFree":61,"interactionStatistic":62},"DigitalDocument",{"name":9,"@type":55},"Person",{"url":39,"name":57,"@type":58},"DocShare","Organization","application/pdf","2026-05-31",true,{"@type":63,"interactionType":64,"userInteractionCount":4},"InteractionCounter",{"@type":65},"ViewAction",{"@type":67,"mainEntity":68},"FAQPage",[69],{"name":70,"@type":71,"acceptedAnswer":72},"How does complex 2 perform under visible light for dye degradation?","Question",{"text":73,"@type":74},"Complex 2 strongly absorbs visible light up to 700 nm and shows obvious activity for the photodegradation of methyl orange.","Answer","https://schema.org",{"og:url":50,"og:type":77,"og:title":13,"og:site_name":57,"og:description":14},"article",{"robots":79,"canonical":50},"index,follow",{"doc_id":7,"site_id":30}]