[{"data":1,"prerenderedAt":-1},["ShallowReactive",2],{"detail-sidebar-cat-0-en-105":3,"doc-seo-466847-105":59,"doc-detail-466847-en":130},{"code":4,"msg":5,"data":6},0,"success",[7,13,18,23,28,33,38,43,48,51,55],{"id":8,"doc_module":4,"doc_module_name":9,"category_name":10,"show_sort_weight":11,"slug":12},1,"Document","Story & Novel",90,"story-novel",{"id":14,"doc_module":4,"doc_module_name":9,"category_name":15,"show_sort_weight":16,"slug":17},2,"Literature",80,"literature",{"id":19,"doc_module":4,"doc_module_name":9,"category_name":20,"show_sort_weight":21,"slug":22},4,"Exam",70,"exam",{"id":24,"doc_module":4,"doc_module_name":9,"category_name":25,"show_sort_weight":26,"slug":27},5,"Comic",60,"comic",{"id":29,"doc_module":4,"doc_module_name":9,"category_name":30,"show_sort_weight":31,"slug":32},6,"Technology",50,"technology",{"id":34,"doc_module":4,"doc_module_name":9,"category_name":35,"show_sort_weight":36,"slug":37},7,"Healthcare",40,"healthcare",{"id":39,"doc_module":4,"doc_module_name":9,"category_name":40,"show_sort_weight":41,"slug":42},8,"Research & Report",30,"research-report",{"id":44,"doc_module":4,"doc_module_name":9,"category_name":45,"show_sort_weight":46,"slug":47},9,"Religion & Spirituality",20,"religion-spirituality",{"id":46,"doc_module":4,"doc_module_name":9,"category_name":49,"show_sort_weight":46,"slug":50},"World Cup","world-cup",{"id":52,"doc_module":4,"doc_module_name":9,"category_name":53,"show_sort_weight":52,"slug":54},10,"Lifestyle","lifestyle",{"id":56,"doc_module":4,"doc_module_name":9,"category_name":57,"show_sort_weight":24,"slug":58},19,"General","general",{"code":4,"msg":60,"data":61},"ok",{"site_id":62,"language":63,"slug":64,"title":65,"keywords":66,"description":67,"schema_data":68,"social_meta":123,"head_meta":125,"extra_data":127,"updated_unix":129},105,"en","nitrates-of-synthetic-cellulose","Nitrates of Synthetic Cellulose","","To reduce reliance on conventional raw materials, the research focuses on alternative cellulose sources and chemical synthesis routes. Cellulose nitrate (NC) was produced by nitrating synthetic cellulose (SC), a new electropolymerized cellulose prepared from aqueous glucose using a tungsten–vanadium heteropolyacid catalyst. SC morphology, functional groups, phase composition, and thermal behavior were characterized by SEM, FT-IR, X-ray diffraction, and coupled TGA/DTA, showing nitration-induced amorphization and enhanced thermal decomposition profiles.",{"@graph":69,"@context":122},[70,84,105],{"@type":71,"itemListElement":72},"BreadcrumbList",[73,77,79,82],{"item":74,"name":75,"@type":76,"position":8},"https://docshare.wps.com","Home","ListItem",{"item":78,"name":9,"@type":76,"position":14},"https://docshare.wps.com/document/",{"item":80,"name":35,"@type":76,"position":81},"https://docshare.wps.com/document/healthcare/",3,{"item":83,"name":65,"@type":76,"position":19},"https://docshare.wps.com/document/nitrates-of-synthetic-cellulose/466847/",{"url":83,"name":65,"@type":85,"image":86,"author":91,"headline":65,"publisher":94,"fileFormat":97,"inLanguage":63,"description":67,"dateModified":98,"datePublished":99,"encodingFormat":97,"isAccessibleForFree":100,"interactionStatistic":101},"DigitalDocument",{"url":87,"@type":88,"width":89,"height":90},"https://docshare.wps.com/thumbnails/nitrates-of-synthetic-cellulose/466847.png","ImageObject",300,407,{"name":92,"@type":93},"4398046744996","Person",{"url":74,"name":95,"@type":96},"DocShare","Organization","application/pdf","2026-10-29","2026-09-30",true,{"@type":102,"interactionType":103,"userInteractionCount":14},"InteractionCounter",{"@type":104},"ViewAction",{"@type":106,"mainEntity":107},"FAQPage",[108,114,118],{"name":109,"@type":110,"acceptedAnswer":111},"What is the main motivation for the study on nitrates of synthetic cellulose?","Question",{"text":112,"@type":113},"The study aims to avoid dependence on conventional raw materials by developing chemical synthesis of cellulose-derived products, specifically cellulose nitrates from synthetically derived cellulose.","Answer",{"name":115,"@type":110,"acceptedAnswer":116},"How was cellulose nitrate synthesized in this work?",{"text":117,"@type":113},"Cellulose nitrate was synthesized by nitration of synthetic cellulose, where the SC was electropolymerized from an aqueous glucose solution using a tungsten–vanadium heteropolyacid catalyst.",{"name":119,"@type":110,"acceptedAnswer":120},"Which techniques were used to characterize the synthetic cellulose and its nitrate derivatives?",{"text":121,"@type":113},"SEM was used for morphological structure, FT-IR for functional groups, X-ray diffraction for phase/crystallinity changes, and coupled TGA/DTA for thermal decomposition behavior.","https://schema.org",{"og:url":83,"og:type":124,"og:title":65,"og:site_name":95,"og:description":67},"article",{"robots":126,"canonical":83},"index,follow",{"doc_id":128,"site_id":62},466847,1792217413,{"code":4,"msg":5,"data":131},{"doc_id":128,"user_id":132,"nickname":92,"user_avatar":66,"doc_module":4,"category_id":34,"category_name":35,"doc_title":65,"doc_description":67,"doc_content":133,"file_id":134,"file_url":135,"file_type":136,"file_size":137,"view_count":14,"is_deleted":4,"is_public":8,"is_downloadable":8,"audit_status":8,"page_count":46,"language":138,"language_code":63,"site_id":62,"html_lang":63,"table_of_contents":139,"faqs":140,"seo_title":141,"seo_description":67,"update_tm":142,"read_time":31,"preview_page_count":4},4398046744996,"Article  \nNitrates of Synthetic Cellulose  \nVera V. Budaeva 1, *, Anna A. Korchagina 1, Yulia A. Gismatulina 1, Ekaterina I. Kashcheyeva 1, Polina A. Gorbatova 1,2, Galina F. Mironova 1, Vladimir N. Zolotukhin 1, Nikolay V. Bychin 3, Inna V. Lyukhanova 4, Lyudmila A. Aleshina 5 and Gennady V. Sakovich 1  \nAcademic Editors: Carmen  \n-Mihaela Popescu, Anamaria Irimia and Jalel Labidi  \nReceived: 17 November 2025  \nRevised: 11 December 2025  \nAccepted: 16 December 2025  \nPublished: 19 December 2025  \nCopyright: © 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.  \n1 Bioconversion Laboratory, Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences (IPCET SB RAS), Biysk 659322, Russia; [yakusheva89_21.ru@mail.ru](yakusheva89_21.ru@mail.ru) (A.A.K.); [julja.gismatulina@rambler.ru](julja.gismatulina@rambler.ru) (Y.A.G.); [massl@mail.ru](massl@mail.ru) (E.I.K.); [1402plngorbatova@mail.ru](1402plngorbatova@mail.ru) (P.A.G.); [yur_galina@mail.ru](yur_galina@mail.ru) (G.F.M.); [zolo-i@mail.ru](zolo-i@mail.ru) (V.N.Z.); [eas_i@mail.ru](eas_i@mail.ru) (G.V.S.)  \n2 Department of Biotechnology, Biysk Technological Institute, Polzunov Altai State Technical University, Biysk 659305, Russia  \n3 Laboratory of Materials Science of Mineral Raw Materials, Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences (IPCET SB RAS), Biysk 659322, Russia; [nbych@yandex.ru](nbych@yandex.ru)  \n4 Radiation Monitoring Sector, Petrozavodsk State University (PetrSU), Petrozavodsk 185910, Russia; [luhanova@yandex.ru](luhanova@yandex.ru)  \n5 Department of Solid-State Physics, Petrozavodsk State University (PetrSU), Petrozavodsk 185910, Russia; [alkftt@mail.ru](alkftt@mail.ru)  \n* [Correspondence: budaeva@ipcet.ru](Correspondence: budaeva@ipcet.ru)  \nAbstract  \nTo avoid dependence on conventional raw materials, global emphasis has been placed on obtaining alternative plant celluloses and the chemical synthesis of cellulose. The use of synthetically derived cellulose as a precursor for cellulose nitrates (NCs) is currently absent in global practice, which underscores the undoubted relevance of this research. Cellulose nitrate (NC) was synthesized in a 138% actual yield by nitration of synthetic cellulose (SC)  \n—a new type of cellulose—prepared by electropolymerization from an aqueous glucose solution in the presence of catalytic tungsten–vanadium heteropolyacid of the 1–12 series with the chemical formula H6[PW 10V2O40 ]: a nitrogen content of 11.83%, a viscosity of 198 mPa·s, a high solubility of 91% in an alcohol–ether solvent, and an ash content of 0.05% . SEM provided a general concept of the morphological structure of SC and SC-derived NC. The initial SC consisted of flat, curly fibers with a smooth surface approximately 10–20 µm wide, with no aggregation observed. The fibers of SC-derived NC had a cylindrical shape with a diameter of up to 25 µm and a rough surface. FT-IR spectroscopy revealed that SC and SC-derived NC have the main functional groups characteristic of classical cellulose (3346, 2901, 1644, 1429, 1162, and 1112 cm−1) and nitrate esters of cellulose (1650, 1278, 832, 747, and 689 cm−1), respectively. For the first time, a full-profile analysis discovered that SC is made up of the monoclinic phase of cellulose Iβ with an antiparallel chain arrangement. SC with a crystallinity index (CrI) of 81–86% was shown to undergo amorphization upon nitration, with the CrI declining to 17% and the crystallite sizes decreasing from 44 × 62 × 59 × 94 Å to 29 × 62 × 26 × 38 Å . Coupled TGA/DTA revealed that SC exhibits a high-temperature endothermic peak of decomposition of 374 ◦ C, with a weight loss of 84% . The thermostable SC-derived NC exhibits a high onset temperature of intense decomposition of 200 ◦ C","cbCaikSyvOK6EZpe","https://ap.wps.com/l/cbCaikSyvOK6EZpe","pdf",2122363,"English","# Abstract\n## Keywords\n# Introduction","[{\"question\":\"What is the main motivation for the study on nitrates of synthetic cellulose?\",\"answer\":\"The study aims to avoid dependence on conventional raw materials by developing chemical synthesis of cellulose-derived products, specifically cellulose nitrates from synthetically derived cellulose.\"},{\"question\":\"How was cellulose nitrate synthesized in this work?\",\"answer\":\"Cellulose nitrate was synthesized by nitration of synthetic cellulose, where the SC was electropolymerized from an aqueous glucose solution using a tungsten–vanadium heteropolyacid catalyst.\"},{\"question\":\"Which techniques were used to characterize the synthetic cellulose and its nitrate derivatives?\",\"answer\":\"SEM was used for morphological structure, FT-IR for functional groups, X-ray diffraction for phase/crystallinity changes, and coupled TGA/DTA for thermal decomposition behavior.\"}]","Nitrates of Synthetic Cellulose | PDF",1790771939]