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A one-pot hydrothermal route forms HPW@MIL-100, followed by an anion-exchange modification using a sulfonic-acid-functionalized ionic liquid to generate [SO3H-(CH2)3-HIM]3PW12O40@MIL-100. MIL-100’s mesoporous cages and microporous windows enable confinement, reducing loss of active species while maintaining MOF crystallinity. Brønsted acid sites together with FeIII Lewis acid centers provide synergistic catalysis. Esterification of oleic acid with ethanol is evaluated, and response surface methodology optimizes reaction conditions.",{"@graph":69,"@context":105},[70,84],{"@type":71,"itemListElement":72},"BreadcrumbList",[73,77,79,82],{"item":74,"name":75,"@type":76,"position":8},"https://docshare.wps.com","Home","ListItem",{"item":78,"name":9,"@type":76,"position":14},"https://docshare.wps.com/document/",{"item":80,"name":40,"@type":76,"position":81},"https://docshare.wps.com/document/research-report/",3,{"item":83,"name":65,"@type":76,"position":19},"https://docshare.wps.com/document/encapsulation-of-heteropolyanion-based-ionic-liquid-within-the-metalorganic-framework-mil-100fe-for-biodiesel-production/27346/",{"url":83,"name":65,"@type":85,"image":86,"author":91,"headline":65,"publisher":94,"fileFormat":97,"inLanguage":63,"description":67,"dateModified":98,"datePublished":99,"encodingFormat":97,"isAccessibleForFree":100,"interactionStatistic":101},"DigitalDocument",{"url":87,"@type":88,"width":89,"height":90},"https://docshare.wps.com/thumbnails/encapsulation-of-heteropolyanion-based-ionic-liquid-within-the-metalorganic-framework-mil-100fe-for-biodiesel-production/27346.png","ImageObject",300,407,{"name":92,"@type":93},"Logic","Person",{"url":74,"name":95,"@type":96},"DocShare","Organization","application/pdf","2026-09-19","2026-05-08",true,{"@type":102,"interactionType":103,"userInteractionCount":81},"InteractionCounter",{"@type":104},"ViewAction","https://schema.org",{"og:url":107,"og:type":108,"og:title":65,"og:site_name":95,"og:description":67},"https://docshare.wps.com/document/encapsulation-of-heteropolyanion-based-ionic-liquid-within-the-metalorganic-framework-mil-100fe-for-biodiesel-production/27346","article",{"robots":110,"canonical":107},"index,follow",{"doc_id":112,"site_id":62},27346,1778274775,{"code":4,"msg":5,"data":115},{"doc_id":112,"user_id":116,"nickname":92,"user_avatar":117,"doc_module":4,"category_id":39,"category_name":40,"doc_title":65,"doc_description":67,"doc_content":66,"file_id":118,"file_url":119,"file_type":120,"file_size":121,"view_count":81,"is_deleted":4,"is_public":8,"is_downloadable":8,"audit_status":8,"page_count":52,"language":122,"language_code":63,"site_id":62,"html_lang":63,"table_of_contents":66,"faqs":66,"seo_title":123,"seo_description":67,"update_tm":113,"read_time":124},1099513958762,"https://ap-avatar.wpscdn.com/avatar/1000023916a998db790?x-image-process=image/resize,m_fixed,w_180,h_180&k=1784791008015729253","cbCaigr20XipP3J0","https://ap.wps.com/l/cbCaigr20XipP3J0","pdf",2311022,"English","Encapsulation of Heteropolyanion-Based Ionic Liquid within the Metal–Organic Framework MIL-100(Fe) for Biodiesel Production | PDF",25]