[{"data":1,"prerenderedAt":-1},["ShallowReactive",2],{"doc-detail-31423":3,"doc-seo-31423":26},{"code":4,"msg":5,"data":6},0,"success",{"doc_id":7,"user_id":8,"nickname":9,"user_avatar":10,"doc_module":4,"category_id":11,"category_name":12,"doc_title":13,"doc_description":14,"file_id":15,"file_url":16,"file_type":17,"file_size":18,"view_count":4,"is_deleted":4,"is_public":19,"is_downloadable":19,"audit_status":19,"page_count":11,"language":20,"language_code":21,"table_of_contents":22,"faqs":23,"seo_title":13,"seo_description":14,"update_tm":24,"read_time":25},31423,1099513958762,"Logic","https://ap-avatar.wpscdn.com/avatar/1000023916a998db790?_k=1776737595927829259",8,"Research & Report","Catalyst Carbonylation: A Hidden, but Essential, Step in Reaction Initiation","Catalyst carbonylation emerges as an underappreciated but essential initiation concept in hydrogen transfer catalysis. The mini-review argues that, across diverse homogeneous hydrogen-transfer systems, catalytic activation and downstream catalyst speciation are dominated by the formation of a carbonyl-metal group. By linking catalyst initiation to decarbonylation of alcohol starting materials and contrasting common template mechanistic views with richer activation pathways, it highlights well-documented case studies. The discussion frames catalyst design implications for mechanism-driven development.","cbCainxHl8efnOHF","https://ap.wps.com/l/cbCainxHl8efnOHF","pdf",627953,1,"English","en","# Introduction\n## Scope of hydrogen transfer and mechanistic complexity\n## Role of catalyst carbonylation\n# How do organics decarbonylate?","[{\"question\":\"What is the central theme of the mini-review on catalyst carbonylation?\",\"answer\":\"Catalyst carbonylation is presented as a hidden but essential step that governs catalyst activation and downstream speciation in certain hydrogen transfer systems.\"},{\"question\":\"How does the formation of a (carbonyl)metal group affect catalyst behavior?\",\"answer\":\"The carbonyl-metal group dominates the downstream speciation of the catalyst system and thereby shapes the catalytic cycle outcomes.\"},{\"question\":\"Is catalyst carbonylation required for hydrogen transfer catalysts?\",\"answer\":\"No; many hydrogen transfer catalysts operate without carbonylation, using different proton- and hydride-transfer mechanisms (inner- and outer-sphere).\"}]",1779483623,20,{"code":4,"msg":27,"data":28},"ok",{"site_id":29,"language":21,"slug":30,"title":13,"keywords":31,"description":14,"schema_data":32,"social_meta":83,"head_meta":85,"extra_data":87,"updated_unix":24},105,"catalyst-carbonylation-a-hidden-but-essential-step-in-reaction-initiation","",{"@graph":33,"@context":82},[34,51,65],{"@type":35,"itemListElement":36},"BreadcrumbList",[37,41,45,48],{"item":38,"name":39,"@type":40,"position":19},"https://docshare.wps.com","Home","ListItem",{"item":42,"name":43,"@type":40,"position":44},"https://docshare.wps.com/document/","Document",2,{"item":46,"name":12,"@type":40,"position":47},"https://docshare.wps.com/document/research-report/",3,{"item":49,"name":13,"@type":40,"position":50},"https://docshare.wps.com/document/catalyst-carbonylation-a-hidden-but-essential-step-in-reaction-initiation/31423/",4,{"url":49,"name":13,"@type":52,"author":53,"headline":13,"publisher":55,"fileFormat":58,"description":14,"dateModified":59,"datePublished":59,"encodingFormat":58,"isAccessibleForFree":60,"interactionStatistic":61},"DigitalDocument",{"name":9,"@type":54},"Person",{"url":38,"name":56,"@type":57},"DocShare","Organization","application/pdf","2026-05-22",true,{"@type":62,"interactionType":63,"userInteractionCount":4},"InteractionCounter",{"@type":64},"ViewAction",{"@type":66,"mainEntity":67},"FAQPage",[68,74,78],{"name":69,"@type":70,"acceptedAnswer":71},"What is the central theme of the mini-review on catalyst carbonylation?","Question",{"text":72,"@type":73},"Catalyst carbonylation is presented as a hidden but essential step that governs catalyst activation and downstream speciation in certain hydrogen transfer systems.","Answer",{"name":75,"@type":70,"acceptedAnswer":76},"How does the formation of a (carbonyl)metal group affect catalyst behavior?",{"text":77,"@type":73},"The carbonyl-metal group dominates the downstream speciation of the catalyst system and thereby shapes the catalytic cycle outcomes.",{"name":79,"@type":70,"acceptedAnswer":80},"Is catalyst carbonylation required for hydrogen transfer catalysts?",{"text":81,"@type":73},"No; many hydrogen transfer catalysts operate without carbonylation, using different proton- and hydride-transfer mechanisms (inner- and outer-sphere).","https://schema.org",{"og:url":49,"og:type":84,"og:title":13,"og:site_name":56,"og:description":14},"article",{"robots":86,"canonical":49},"index,follow",{"doc_id":7,"site_id":29}]