[{"data":1,"prerenderedAt":-1},["ShallowReactive",2],{"doc-detail-35750":3,"doc-seo-35750":29},{"code":4,"msg":5,"data":6},0,"success",{"doc_id":7,"user_id":8,"nickname":9,"user_avatar":10,"doc_module":4,"category_id":11,"category_name":12,"doc_title":13,"doc_description":14,"doc_content":15,"file_id":16,"file_url":17,"file_type":18,"file_size":19,"view_count":4,"is_deleted":4,"is_public":20,"is_downloadable":20,"audit_status":20,"page_count":21,"language":22,"language_code":23,"site_id":24,"html_lang":23,"table_of_contents":25,"faqs":26,"seo_title":13,"seo_description":14,"update_tm":27,"read_time":28},35750,687197100911,"Himbo","https://ap-avatar.wpscdn.com/avatar/a000239b6f1da00475?x-image-process=image/resize,m_fixed,w_180,h_180&k=1782698725881665579",8,"Research & Report","Alternative Synthetic Methodology for Amide Formation in Post-Synthetic Modification of TiMIL125-NH2","Robust metal–organic framework materials enable property tuning through post-synthetic modification, especially by functionalizing amino groups. The study presents test modifications of Ti-MIL125-NH2 to adjust porous and catalytic behavior and reports the first use of a mild amide synthesis method for post-synthetic modification. MIL125-NH2 is characterized by Rietveld refinement and a structural model linking inorganic Ti-oxide clusters with aminoterephthalate linkers.","","cbCaif9gNLMwat9o","https://ap.wps.com/l/cbCaif9gNLMwat9o","pdf",1631600,1,4,"English","en",105,"# Introduction\n## Post-synthetic modification and amine functionality\n# Materials and Methods\n## Synthesis of Ti-MIL125-NH2\n## Structural characterization and Rietveld refinement\n# Structural Overview\n## Inorganic clusters and organic linkers\n## Pore/cavity description","[{\"question\":\"What is the main objective of the work on TiMIL125-NH2?\",\"answer\":\"To perform post-synthetic modification studies on Ti-MIL125-NH2, demonstrating an unreported way to synthesize amide groups and introduce functional groups into the material.\"},{\"question\":\"How is Ti-MIL125-NH2 synthesized in the study?\",\"answer\":\"It is synthesized using a scaled-up literature method from 2-aminoterephthalic acid and titanium isopropoxide in a DMF–MeOH solvent mixture.\"},{\"question\":\"How is the structure of MIL125-NH2 confirmed and analyzed?\",\"answer\":\"Rietveld refinement is performed using an amino-modified structural model based on the known MIL125 structure, confirming the represented structure and describing the cluster and linker arrangement.\"}]",1782594046,10,null]